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Synthesis and characterization of a composite polymeric material including chelating agent for adsorption of uranyl ions.

Journal of hazardous materials (2017-06-09)
Selçuk Şimşek, Zeynep Mine Şenol, Halil İbrahim Ulusoy
RÉSUMÉ

In this study, a versatile polymeric material was synthesized by grafting Calcon Carboxylic Acid (CCA), which is known as a chelating agent for some metal ions, to polyacrylamide (PAA) structure. Thus, the adsorptive properties of inert PAA polymer were significantly improved owing to this procedure. The obtained new material, CCA-g-PAA, was characterized by point zero charge (PZC), FTIR, SEM, and UV-VIS-NIR analysis. The adsorption properties of new material were investigated comprehensively and experimental variables were optimized such as pH, temperature, time, and concentration. Experimental data were evaluated by using theoretical adsorption models. The maximum adsorption capacity of material was calculated as 0.079molkg

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Sigma-Aldrich
Calconcarboxylic acid, suitable for use as an indicator for the titration of calcium