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Strategies for Enhancing the Catalytic Performance of Metal-Organic Frameworks in the Fixation of CO

ChemSusChem (2016-12-20)
Masoumeh Taherimehr, Ben Van de Voorde, Lik H Wee, Johan A Martens, Dirk E De Vos, Paolo P Pescarmona
RÉSUMÉ

Metal-organic frameworks (MOFs) with accessible Lewis acid sites are finding increasing application in the field of heterogeneous catalysis. However, the structural instability of MOFs when they are exposed to high temperature and/or high pressure often limits their applicability. In this study, two strategies were applied to achieve a MOF catalyst with high stability, activity and selectivity in the reaction of CO

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1,1,1-Trifluoro-5,5-dimethyl-2,4-hexanedione, 98%