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  • Six-component reactions for the stereoselective synthesis of 3-arylidene-2-oxindoles via sequential one-pot Ugi/Heck carbocyclization/Sonogashira/nucleophilic addition.

Six-component reactions for the stereoselective synthesis of 3-arylidene-2-oxindoles via sequential one-pot Ugi/Heck carbocyclization/Sonogashira/nucleophilic addition.

The Journal of organic chemistry (2010-04-15)
Morteza Bararjanian, Saeed Balalaie, Frank Rominger, Barahman Movassagh, Hamid Reza Bijanzadeh
RÉSUMÉ

An efficient palladium-catalyzed protocol for the synthesis of 3-arylidene-2-oxindoles has been developed. In this approach, a sequential one-pot six-component reaction via Ugi/Heck carbocyclization/Sonogashira/nucleophilic addition was used for the synthesis of the desired skeleton.

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Sigma-Aldrich
2-Oxindole, 97%