278742

(1S,2R,5S)-(+)-Menthyl (R)-p-toluenesulfinate

98%

• Synonyme(s) : (R)-(+)-Menthyl p-toluenesulfinate
• Formule empirique (notation de Hill): C₁₇H₂₆O₂S
• Numéro CAS: 91796-57-5
• Poids moléculaire : 294.45
• Code UNSPSC : 12352000
• ID de substance PubChem : 24856827
• Nomenclature NACRES : NA.22

Propriétés

• Pureté: 98%
• Forme: solid
• Activité optique: [α]20/D +200°, c = 2 in acetone
• Pf: 104-106 °C (lit.)
• Température de stockage: 2-8°C
• Chaîne SMILES: C[C@H]1CC[C@H](C(C)C)[C@H](C1)OS(=O)c2ccc(C)cc2
• InChI: 1S/C17H26O2S/c1-12(2)16-10-7-14(4)11-17(16)19-20(18)15-8-5-13(3)6-9-15/h5-6,8-9,12,14,16-17H,7,10-11H2,1-4H3/t14-,16+,17-,20+/m0/s1
• Clé InChI: NQICGNSARVCSGJ-DZIWXPPMSA-N

Description

Application

(1S,2R,5S)-(+)-Menthyl (R)-p-toluenesulfinate can be used:

• As a chiral electrophile in the synthesis of fluorescent triazolopyridine ligands.
• To prepare various sulfinimines, which are further used in the synthesis of α-aminophosphonic acids by reacting with borane complexes.
• In one of the key synthetic steps for the synthesis of (S)-(+)-ethyl β-amino-3-pyridinepropanoate, a component of an antiplatelet agent.

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Gloves, type N95 (US)