- Recyclable polyurea-microencapsulated Pd(0) nanoparticles: an efficient catalyst for hydrogenolysis of epoxides.
Recyclable polyurea-microencapsulated Pd(0) nanoparticles: an efficient catalyst for hydrogenolysis of epoxides.
Organic letters (2003-11-25)
Steven V Ley, Claire Mitchell, David Pears, Chandrashekar Ramarao, Jin-Quan Yu, Wuzong Zhou
PMID14627410
ABSTRACT
[reaction: see text] Pd nanoparticles (approximately 2 nm in size) microencapsulated in polyurea is an efficient and recyclable catalyst for reductive ring-opening hydrogenolysis of epoxides, using either HCOOH/Et(3)N or H(2) as a hydrogen donor.
MATERIALS
Product Number
Brand
Product Description
Sigma-Aldrich
Pd(0) EnCat® 30NP, wet, nanoparticles, extent of labeling: 0.4 mmol/g Pd(0) loading (dry basis)