- Graphite powder and multiwalled carbon nanotubes chemically modified with 4-nitrobenzylamine.
Graphite powder and multiwalled carbon nanotubes chemically modified with 4-nitrobenzylamine.
Chemphyschem : a European journal of chemical physics and physical chemistry (2005-03-09)
Gregory G Wildgoose, Shelley J Wilkins, Gareth R Williams, Robert R France, David L Carnahan, Li Jiang, Timothy G J Jones, Richard G Compton
PMID15751359
ABSTRACT
We demonstrate that graphite powder and multiwalled carbon nanotubes (MWCNTs) can be derivatised by 4-nitrobenzylamine (4-NBA) simply by stirring the graphite powder or MWCNTs in a solution of acetonitrile containing 10 mM 4-NBA. We propose that 4-NBA partially intercalates at localised edge-plane or edge-plane-like defect sites and this hypothesis with a range of experimental data provided by electrochemistry in both aqueous and nonaqueous media, electron microscopy and X-ray powder diffraction.
MATERIALS