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919349

Sigma-Aldrich

NaDT

Synonym(s):

Sodium decatungstate

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About This Item

Empirical Formula (Hill Notation):
Na4O32W10
CAS Number:
126752-51-0
Molecular Weight:
2442.34
UNSPSC Code:
12352103
NACRES:
NA.22

form

powder

Quality Level

100

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

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Application

NaDT is a decatungstate photocatalyst with demonstrated uses in the trifluoromethylation of aliphatic C-H bonds as wells the selective C-H fluorination of unprotected peptides.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

The merger of decatungstate and copper catalysis to enable aliphatic C(sp3)-H trifluoromethylation

Site-Selective, Late-Stage C-H 18F-Fluorination on Unprotected Peptides for Positron Emission Tomography Imaging

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Product No.
Description
Pricing

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Certificates of Analysis (COA)

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Patrick J Sarver et al.
Nature chemistry, 12(5), 459-467 (2020-03-24)
The introduction of a trifluoromethyl (CF3) group can dramatically improve a compound's biological properties. Despite the well-established importance of trifluoromethylated compounds, general methods for the trifluoromethylation of alkyl C-H bonds remain elusive. Here we report the development of a dual-catalytic
Zheliang Yuan et al.
Angewandte Chemie (International ed. in English), 57(39), 12733-12736 (2018-08-08)
Peptides are often ideal ligands for diagnostic molecular imaging due to their ease of synthesis and tuneable targeting properties. However, labelling unmodified peptides with 18 F for positron emission tomography (PET) imaging presents a number of challenges. Here we show

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