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346187

Sigma-Aldrich

Trioctylphosphine oxide

technical grade, 90%

Synonym(s):

(Oct)3PO, TOPO®

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About This Item

Linear Formula:
[CH3(CH2)7]3PO
CAS Number:
78-50-2
Molecular Weight:
386.63
Beilstein:
1796648
EC Number:
201-121-3
MDL number:
MFCD00002083
UNSPSC Code:
12352119
PubChem Substance ID:
24861379
NACRES:
NA.22

grade

technical grade

Assay

90%

form

solid

bp

201-202 °C/2 mmHg (lit.)

mp

50-52 °C (lit.)

functional group

phosphine oxide

SMILES string

CCCCCCCCP(=O)(CCCCCCCC)CCCCCCCC

InChI

1S/C24H51OP/c1-4-7-10-13-16-19-22-26(25,23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

InChI key

ZMBHCYHQLYEYDV-UHFFFAOYSA-N

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Application

Used as an extraction or stabilizing agent; also useful as a capping ligand for the production of quantum dots such as CdSe.

Legal Information

TOPO is a registered trademark of Life Technologies

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H315,H318,H412

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

446.0 °F - closed cup

Flash Point(C)

230 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Aditya Sharma et al.
Analytical chemistry, 84(7), 3082-3089 (2012-03-03)
We present results of the studies relating to preparation of Langmuir-Blodgett (LB) monolayers of tri-n-octylphosphine oxide-capped cadmium selenide quantum dots (QCdSe) onto indium-tin oxide (ITO) coated glass substrate. The monolayer behavior has been studied at the air-water interface under various
Harikrishna Bavireddi et al.
The Analyst, 137(21), 5123-5127 (2012-09-25)
Highly fluorescent water soluble glyco-quantum dots were synthesized using a sonochemical procedure. The synthetic approach is based on specific host-guest interactions between β-cyclodextrin (β-CD) and trioctylphosphine oxide (TOPO) surfactant on quantum dots. The modified QDs were analyzed by a combination
Sanjeev Kumar Mahto et al.
Toxicology in vitro : an international journal published in association with BIBRA, 24(4), 1070-1077 (2010-04-07)
With the widespread use of quantum dots (QDs), the likelihood of exposure to QDs has been assumed to have increased substantially. Recently, QDs have been employed in numerous biological and medical applications. However, there is a lack of toxicological data
Raju Banda et al.
Journal of hazardous materials, 213-214, 1-6 (2012-02-18)
The separation and recovery of Mo and Co from the synthetic chloride leach liquors of petroleum refining catalyst has been investigated by employing TOPO and Alamine 308 as extractants. The synthetic leach liquor contained Mo 394 mg/L, Al 1782 mg/L
Huwei Feng et al.
Frontiers in chemistry, 8, 266-266 (2020-05-07)
Quantum dot light-emitting diodes (QLEDs) have been considered as the most promising candidate of light sources for the new generation display and solid-state lighting applications. Especially, the performance of visible QLEDs based on II-VI quantum dots (QDs) has satisfied the
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