- Recent advances in homogeneous nickel catalysis.
Recent advances in homogeneous nickel catalysis.
Nature (2014-05-16)
Sarah Z Tasker, Eric A Standley, Timothy F Jamison
PMID24828188
ABSTRACT
Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions. In recent years, these properties have been increasingly understood and used to perform transformations long considered exceptionally challenging. Here we discuss some of the most recent and significant developments in homogeneous nickel catalysis, with an emphasis on both synthetic outcome and mechanism.
MATERIALS
Product Number
Brand
Product Description
Sigma-Aldrich
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II), ≥95%
Nickel, foil, 15mm disks, thickness 0.075mm, annealed, 99%
Nickel, tube, 100mm, outside diameter 0.75mm, inside diameter 0.59mm, wall thickness 0.08mm, hard, 99.5%
Nickel, foil, 10mm disks, thickness 0.30mm, as rolled, 99.98%
Nickel, foil, 1m coil, thickness 0.15mm, annealed, 99%
Nickel, rod, 200mm, diameter 20.0mm, 99%
Nickel, foil, 10mm disks, thickness 0.125mm, as rolled, 100%
Nickel, foil, 1m coil, thickness 0.3mm, coil width 1mm, as rolled, 99%
Nickel, sphere, 100pcs, diameter 0.76mm, precision sphere grade 200, 99%
Nickel, rod, 500mm, diameter 9.5mm, 99%
Nickel, foil, 15mm disks, thickness 0.25mm, as rolled, 100%
Nickel, tube, 100mm, outside diameter 3.25mm, inside diameter 3.05mm, wall thickness 0.1mm, hard, 99.5%
Nickel, tube, 100mm, outside diameter 0.8mm, inside diameter 0.5mm, wall thickness 0.15mm, as drawn, 99.5%
Nickel, tube, 1000mm, outside diameter 3.0mm, inside diameter 2.4mm, wall thickness 0.3mm, hard, 99.5%
Nickel, foil, 1m coil, thickness 0.003mm, 99.95%
Nickel, foil, 15mm disks, thickness 0.5mm, as rolled, 99.99+%
Nickel, rod, 50mm, diameter 5.0mm, 99.99+%
Nickel, tube, 100mm, outside diameter 2.5mm, inside diameter 2mm, wall thickness 0.25mm, hard, 99.5%
Nickel, tube, 200mm, outside diameter 0.65mm, inside diameter 0.384mm, wall thickness 0.133mm, as drawn, 99.5%
Nickel, tube, 100mm, outside diameter 0.35mm, inside diameter 0.3mm, wall thickness 0.025mm, hard, 99.5%
Nickel, foil, 1m coil, thickness 0.125mm, annealed, 99.98%
Nickel, foil, 10mm disks, thickness 0.3mm, as rolled, 100%
Nickel, foil, 15mm disks, thickness 0.025mm, annealed, 99%
Nickel, rod, 50mm, diameter 10.0mm, 99.99+%