- Construction of 1,5-enynes by stereospecific Pd-catalyzed allyl-propargyl cross-couplings.
Construction of 1,5-enynes by stereospecific Pd-catalyzed allyl-propargyl cross-couplings.
Journal of the American Chemical Society (2012-05-19)
Michael J Ardolino, James P Morken
PMID22594398
ABSTRACT
The palladium-catalyzed cross-coupling of chiral propargyl acetates and allyl boronates delivers chiral 1,5-enynes with excellent levels of chirality transfer and can be applied across a broad range of substrates.