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Brain-penetrating 2-aminobenzimidazole H(1)-antihistamines for the treatment of insomnia.

Bioorganic & medicinal chemistry letters (2009-06-26)
Timothy Coon, Wilna J Moree, Binfeng Li, Jinghua Yu, Said Zamani-Kord, Siobhan Malany, Mark A Santos, Lisa M Hernandez, Robert E Petroski, Aixia Sun, Jenny Wen, Sue Sullivan, Jason Haelewyn, Michael Hedrick, Samuel J Hoare, Margaret J Bradbury, Paul D Crowe, Graham Beaton
ZUSAMMENFASSUNG

The benzimidazole core of the selective non-brain-penetrating H(1)-antihistamine mizolastine was used to identify a series of brain-penetrating H(1)-antihistamines for the potential treatment of insomnia. Using cassette PK studies, brain-penetrating H(1)-antihistamines were identified and in vivo efficacy was demonstrated in a rat EEG/EMG model. Further optimization focused on strategies to attenuate an identified hERG liability, leading to the discovery of 4i with a promising in vitro profile.

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Sigma-Aldrich
2-Aminobenzimidazol, 97%