Direkt zum Inhalt
Merck
Alle Fotos(2)

Dokumente

277053

Sigma-Aldrich

(S)-(+)-2-(Methoxymethyl)pyrrolidin

99%

Synonym(e):

O-Methyl-L-prolinol, SMP

Anmeldenzur Ansicht organisationsspezifischer und vertraglich vereinbarter Preise
Alle Fotos(2)

About This Item

Empirische Formel (Hill-System):
C6H13NO
CAS-Nummer:
63126-47-6
Molekulargewicht:
115.17
Beilstein:
3587324
MDL-Nummer:
MFCD00010408
UNSPSC-Code:
12352005
PubChem Substanz-ID:
24856730
NACRES:
NA.22

Assay

99%

Form

liquid

Optische Aktivität

[α]20/D +2.4°, c = 2 in benzene

Brechungsindex

n20/D 1.4457 (lit.)

bp

62 °C/40 mmHg (lit.)

Dichte

0.933 g/mL at 25 °C (lit.)

SMILES String

COC[C@@H]1CCCN1

InChI

1S/C6H13NO/c1-8-5-6-3-2-4-7-6/h6-7H,2-5H2,1H3/t6-/m0/s1

InChIKey

CHPRFKYDQRKRRK-LURJTMIESA-N

Anwendung

Chiral auxiliary for asymmetric synthesis of propargyl alcohols and 4-nitrocyclohexanones, and for asymmetric Michael additions to enones.
(S)-(+)-2-(Methoxymethyl)pyrrolidine may be used to prepare planar chiral 2-phospha[3]ferrocenophanes. It may also be used as an organocatalyst in the cross-aldol reaction of dihydroxyacetone with p-nitrobenzaldehyde to form the corresponding polyol. SMP reacts with benzoylformic acid to form (S)-N-benzoylformyl-2-(methoxymethyl)-pyrrolidine.

Piktogramme

FlameExclamation mark
GHS02,GHS07

Signalwort

Warning

Gefahreneinstufungen

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 3

Flammpunkt (°F)

113.0 °F - closed cup

Flammpunkt (°C)

45 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

Besitzen Sie dieses Produkt bereits?

In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Cian Vyas et al.
Materials science & engineering. C, Materials for biological applications, 118, 111433-111433 (2020-12-02)
Polycaprolactone (PCL) scaffolds have been widely investigated for tissue engineering applications, however, they exhibit poor cell adhesion and mechanical properties. Subsequently, PCL composites have been produced to improve the material properties. This study utilises a natural material, Bombyx mori silk
Roberta Fraioli et al.
Scientific reports, 7(1), 16363-16363 (2017-11-29)
Engineering the interface between biomaterials and tissues is important to increase implant lifetime and avoid failures and revision surgeries. Permanent devices should enhance attachment and differentiation of stem cells, responsible for injured tissue repair, and simultaneously discourage bacterial colonization; this
Matthias Liebrand et al.
NeuroImage, 223, 117363-117363 (2020-09-13)
Non-invasive transcranial stimulation of cerebellum and primary motor cortex (M1) has been shown to enhance motor learning. However, the mechanisms by which stimulation improves learning remain largely unknown. Here, we sought to shed light on the neural correlates of transcranial
Lian Xia et al.
Journal of chromatography. A, 1500, 24-31 (2017-04-15)
A magnetic, mesoporous core/shell structured Fe
D Kawauchi et al.
Oncogene, 36(37), 5231-5242 (2017-05-16)
Group3 medulloblastoma (MB
Alle zugehörigen Dokumente anzeigen

Unser Team von Wissenschaftlern verfügt über Erfahrung in allen Forschungsbereichen einschließlich Life Science, Materialwissenschaften, chemischer Synthese, Chromatographie, Analytik und vielen mehr..

Setzen Sie sich mit dem technischen Dienst in Verbindung.