Palladium-catalysed hydroxylation and alkoxylation.

Palladium-catalysed hydroxylation and alkoxylation.

Chemical Society reviews (2011-06-07)

Stephan Enthaler, Anna Company

RESUMEN

The formation of oxygen-carbon bonds is one of the fundamental transformations in organic synthesis. In this regard the application of palladium-based catalysts has been extensively studied during recent years. Nowadays it is an established methodology and the success has been proven in manifold synthetic procedures. This tutorial review summarizes the advances on palladium-catalysed C-O bond formation, means hydroxylation and alkoxylation reactions.

MATERIALES

Referencia del producto

Marca

Descripción del producto

203939

Sigma-Aldrich

Palladium, powder, 99.995% trace metals basis

326666

Sigma-Aldrich

Palladium, powder, <1 μm, ≥99.9% trace metals basis

686468

Sigma-Aldrich

Palladium, nanopowder, <25 nm particle size (TEM), ≥99.5%

203998

Sigma-Aldrich

Palladium, powder or granules, 99.99% trace metals basis

267120

Sigma-Aldrich

Palladium, foil, thickness 0.025 mm, 99.9% trace metals basis

267082

Sigma-Aldrich

Palladium, sponge, 99.9% trace metals basis

464651

Sigma-Aldrich

Palladium, powder, <75 μm, 99.9% trace metals basis

348694

Sigma-Aldrich

Palladium, wire, diam. 0.5 mm, 99.9% trace metals basis

348678

Sigma-Aldrich

Palladium, foil, thickness 1.0 mm, 99.9% trace metals basis

267112

Sigma-Aldrich

Palladium, wire, diam. 1.0 mm, 99.9% trace metals basis

287474

Sigma-Aldrich

Palladium, foil, thickness 0.5 mm, 99.9% trace metals basis

348643

Sigma-Aldrich

Palladium, foil, thickness 0.25 mm, 99.98% trace metals basis

GF39094904

Palladium, tube, 50mm, outside diameter 1.0mm, inside diameter 0.8mm, wall thickness 0.1mm, as drawn, 99.95%

373206

Sigma-Aldrich

Palladium, evaporation slug, diam. × L 0.6 cm × 0.6 cm, 99.95% trace metals basis

GF19845120

Palladium, rod, 50mm, diameter 4.0mm, 99.95%

GF81435146

Palladium, rod, 100mm, diameter 2.0mm, 99.95%

GF73152648

Palladium, rod, 10mm, diameter 6.0mm, 99.95%

GF17478445

Palladium, foil, 25x25mm, thickness 0.50mm, as rolled, 99.99+%

GF99541985

Palladium, tube, 200mm, outside diameter 2.0mm, inside diameter 1.6mm, wall thickness 0.2mm, as drawn, 99.95%

GF89451489

Palladium, rod, 50mm, diameter 2.0mm, 99.95%

GF04041403

Palladium, wire reel, 1m, diameter 0.05mm, as drawn, 99.9%

GF68272588

Palladium, rod, 25mm, diameter 6.0mm, 99.95%

GF61398197

Palladium, wire reel, 0.05m, diameter 1.0mm, hard, 99.95%

GF03781863

Palladium, foil, light tested, 25x25mm, thickness 0.025mm, as rolled, 99.95%

GF42154051

Palladium, foil, light tested, 50x50mm, thickness 0.025mm, as rolled, 99.99+%

GF84888297

Palladium, microfoil, disks, 25mm, thinness 0.25μm, specific density 303.4μg/cm², permanent mylar 3.5μm support, 99.99%

GF90054659

Palladium, rod, 50mm, diameter 6.0mm, 99.95%

GF35196330

Palladium, tube, 100mm, outside diameter 2.0mm, inside diameter 1.6mm, wall thickness 0.2mm, as drawn, 99.95%

GF50683631

Palladium, tube, 50mm, outside diameter 2.0mm, inside diameter 1.6mm, wall thickness 0.2mm, as drawn, 99.95%

GF65598171

Palladium, wire reel, 0.2m, diameter 0.25mm, as drawn, 99.99+%