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Merck

Synthesis of new UV-B light absorbents: (Acetylphenyl)glycosides with antioxidant activities.

Bioorganic & medicinal chemistry letters (2008-05-31)
Takashi Otani, Tetsu Tsubogo, Naoki Furukawa, Takao Saito, Katsumi Uchida, Kanako Iwama, Yuki Kanai, Hirofumi Yajima
RESUMEN

m-Acetylphenyl-beta-d-glucopyranosides and m-acetylphenyl-alpha/beta-d-mannopyranosides were synthesized by the Koenigs-Knorr, Mitsunobu, and Helferich reactions as key glycosylation reactions, respectively. Their spectroscopic properties and antioxidative activities were characterized as potential ultraviolet B-ray absorbents.

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Sigma-Aldrich
3′-Hydroxyacetophenone, 97%
Sigma-Aldrich
3′-Hydroxyacetophenone, ≥99%