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Merck

911615

Sigma-Aldrich

[Ru(η33-C10H16)Cl(μ2-O,O-O2CMe)]

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About This Item

Fórmula empírica (notación de Hill):
C12H19ClO2Ru
Número de CAS:
Peso molecular:
331.80
UNSPSC Code:
12161600

form

powder or crystals

mp

141-147 °C

Application

[Ru(η33-C10H16)Cl(μ2-O,O-O2CMe)] is a ruthenium catalyst developed for the redox-neutral isomerization of allylic alcohols to saturated carbonyls under physiological conditions. This bioorthoganol and biocompatible catalyst has also been shown to be active inside living cells.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Nicolás Ríos-Lombardía et al.
Angewandte Chemie (International ed. in English), 55(30), 8691-8695 (2016-06-04)
The ruthenium-catalyzed redox isomerization of allylic alcohols was successfully coupled with the enantioselective enzymatic ketone reduction (mediated by KREDs) in a concurrent process in aqueous medium. The overall transformation, formally the asymmetric reduction of allylic alcohols, took place with excellent
Cristian Vidal et al.
Journal of the American Chemical Society, 141(13), 5125-5129 (2019-03-21)
Tailored ruthenium(IV) complexes can catalyze the isomerization of allylic alcohols into saturated carbonyl derivatives under physiologically relevant conditions, and even inside living mammalian cells. The reaction, which involves ruthenium-hydride intermediates, is bioorthogonal and biocompatible, and can be used for the
Nicolás Ríos-Lombardía et al.
Chemical communications (Cambridge, England), 51(54), 10937-10940 (2015-06-13)
The ruthenium-catalysed isomerisation of allylic alcohols was coupled, for the first time, with asymmetric bioamination in a one-pot process in an aqueous medium. In the cases involving prochiral ketones, the ω-TA exhibited excellent enantioselectivity, identical to that observed in the

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