- Synthesis of atromentin and its O-alkylated natural products.
Synthesis of atromentin and its O-alkylated natural products.
Bioscience, biotechnology, and biochemistry (2010-11-13)
Yue Qi Ye, Hiroyuki Koshino, Naoki Abe, Takemichi Nakamura, Daisuke Hashizume, Shunya Takahashi
PMID21071857
ABSTRACT
The structure of a long-known natural pigment, atromentin, was established by a total synthesis based on double Suzuki-Miyaura coupling and by a single-crystal X-ray analysis of the synthetic sample thereby obtained. A similar strategy including ceric ammonium nitrate (CAN) oxidation was applied to prepare 2-O-methoxyatromentin and thelephantin I.
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