sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

266981

Sigma-Aldrich

Nickel, powder, <50 μm, 99.7% trace metals basis

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

GF85965250

Nickel, tube, 100mm, outside diameter 3.0mm, inside diameter 2.4mm, wall thickness 0.3mm, hard, 99.5%

GF60907091

Nickel, wire reel, 20m, diameter 1.0mm, hard, 99.98%

GF57875417

Nickel, tube, 200mm, outside diameter 5.9mm, inside diameter 5.65mm, wall thickness 0.125mm, hard, 99.5%

GF23066197

Nickel, tube, 200mm, outside diameter 0.8mm, inside diameter 0.64mm, wall thickness 0.08mm, as drawn, 99.5%

GF64460099

Nickel, tube, 1000mm, outside diameter 1.8mm, inside diameter 1.6mm, wall thickness 0.1mm, hard, 99.5%

GF46969587

Nickel, wire reel, 5m, diameter 0.5mm, as drawn, 99%

GF47594144

Nickel, tube, 1000mm, outside diameter 0.8mm, inside diameter 0.3mm, wall thickness 0.25mm, as drawn, 99.5%

GF42115115

Nickel, foil, 15mm disks, thickness 0.5mm, as rolled, 99.99+%

GF63069419

Nickel, foil, 25mm disks, thickness 0.15mm, annealed, 99%

GF38850576

Nickel, wire reel, 50m, diameter 0.025mm, as drawn, 99.6+%

GF29666920

Nickel, foil, 20m coil, thickness 0.125mm, coil width 1mm, as rolled, 99%

GF93376941

Nickel, tube, 100mm, outside diameter 0.75mm, inside diameter 0.59mm, wall thickness 0.08mm, hard, 99.5%

GF43517976

Nickel, wire reel, 20m, diameter 2.0mm, hard, 99.98%

GF05191578

Nickel, foil, 15mm disks, thickness 0.20mm, annealed, 99%

GF44029425

Nickel, foil, 1m coil, thickness 0.15mm, annealed, 99%

GF04942414

Nickel, wire reel, 5m, diameter 0.5mm, hard, 99.98%

GF74554780

Nickel, wire reel, 50m, diameter 0.5mm, as drawn, 99%

GF61415030

Nickel, tube, 200mm, outside diameter 2.4mm, inside diameter 2.248mm, wall thickness 0.076mm, hard, 99.5%

GF39981437

Nickel, wire reel, 5m, diameter 0.25mm, as drawn, 99.99+%

GF50019937

Nickel, foil, 6mm disks, thickness 0.009mm, 99.95%

GF84292364

Nickel, wire reel, 2m, diameter 0.75mm, as drawn, 99.99+%

GF01966732

Nickel, wire reel, 5m, diameter 1.0mm, as drawn, 99%

GF57335148

Nickel, wire reel, 50m, diameter 0.5mm, hard, 99.98%

GF33022381

Nickel, wire reel, 5m, diameter 0.0125mm, Stress relieved, 99.98%