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Key Documents

30755-M

Sigma-Aldrich

Perchloric acid

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., 70.0-72.0%

Synonym(s):

PCA

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About This Item

Linear Formula:
HClO4
CAS Number:
Molecular Weight:
100.46
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.21

grade

ACS reagent
puriss. p.a.

Quality Level

Agency

USP/NF
reag. ISO
reag. Ph. Eur.

Assay

70.0-72.0%

form

liquid

impurities

≤0.00005% free chlorine (Cl)
≤0.0001% heavy metals (as Pb)
≤0.001% total nitrogen (N)

ign. residue

≤0.003% (as SO4)

color

APHA: ≤10

density

1.670 g/cm3

anion traces

chlorate (ClO3-): ≤0.001%
chloride (Cl-): ≤0.0003%
phosphate, silicate (as SiO2): ≤0.0005%
sulfate (SO42-): ≤0.001%

cation traces

Ag: ≤0.00001%
Al: ≤0.000005%
As: ≤0.000005%
Ba: ≤0.000002%
Be: ≤0.000002%
Bi: ≤0.00001%
Ca: ≤0.00005%
Cd: ≤0.000005%
Co: ≤0.000005%
Cu: ≤0.00001%
Fe: ≤0.0001%
Ge: ≤0.000005%
K: ≤0.00001%
Li: ≤0.000002%
Mg: ≤0.00005%
Mn: ≤0.000002%
Mo: ≤0.000005%
Ni: ≤0.00001%
Pb: ≤0.000005%
Sr: ≤0.000002%
Ti: ≤0.00001%
Tl: ≤0.000005%
V: ≤0.000005%
Zn: ≤0.00001%
Zr: ≤0.00001%

SMILES string

OCl(=O)(=O)=O

InChI

1S/ClHO4/c2-1(3,4)5/h(H,2,3,4,5)

InChI key

VLTRZXGMWDSKGL-UHFFFAOYSA-N

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Application

Perchloric acid is a strong acid that can be used as a reagent in the oxidative esterification of aldehydes. It can also be used as a catalyst for the condensation of amines and aldehydes to synthesize arylimines.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Ox. Liq. 1 - Skin Corr. 1A - STOT RE 2

Target Organs

Thyroid

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Peroxovanadium-catalyzed oxidative esterification of aldehydes
Gopinath R, et al.
The Journal of Organic Chemistry, 68, 2944-2947 (2003)
Alexander Duscha et al.
Cell, 180(6), 1067-1080 (2020-03-12)
Short-chain fatty acids are processed from indigestible dietary fibers by gut bacteria and have immunomodulatory properties. Here, we investigate propionic acid (PA) in multiple sclerosis (MS), an autoimmune and neurodegenerative disease. Serum and feces of subjects with MS exhibited significantly
Taro Takami et al.
Cancer research, 67(20), 9844-9851 (2007-10-19)
Hepatocyte growth factor (HGF) has been reported to have both positive and negative effects on carcinogenesis. Here, we show that the loss of c-Met signaling in hepatocytes enhanced rather than suppressed the early stages of chemical hepatocarcinogenesis. c-Met conditional knockout

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