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109576

Sigma-Aldrich

1,1′-Dimethylferrocene

95%

Synonym(s):

Bis(methylcyclopentadienyl)iron

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About This Item

Empirical Formula (Hill Notation):
C12H14Fe
CAS Number:
1291-47-0
Molecular Weight:
214.08
EC Number:
215-067-3
MDL number:
MFCD00001425
UNSPSC Code:
12161600
PubChem Substance ID:
24846924
NACRES:
NA.22

Assay

95%

form

solid

reaction suitability

core: iron
reagent type: catalyst

mp

37-40 °C (lit.)

SMILES string

[Fe].C[C]1[CH][CH][CH][CH]1.C[C]2[CH][CH][CH][CH]2

InChI

1S/2C6H7.Fe/c2*1-6-4-2-3-5-6;/h2*2-5H,1H3;

InChI key

GJFIEPAJMYPAGC-UHFFFAOYSA-N

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

226.4 °F - closed cup

Flash Point(C)

108.00 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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P C Pandey et al.
Analytical biochemistry, 252(1), 136-142 (1997-11-05)
This article describes the research investigations on the development of the amperometric biosensors based on mediated bioelectrochemistry. The mediated bioelectrochemistry involving horseradish peroxidase and glucose oxidase within the graphite paste is reported. The enzyme horseradish peroxidase together with electrochemical mediator
M Wenzel et al.
Zeitschrift fur Naturforschung. C, Journal of biosciences, 43(11-12), 963-966 (1988-11-01)
The relative stabilities of different ferricinium cations were studied in buffer or serum-containing solution and in vivo and compared with their cytostatic effects in cultures of Yoshida ascites tumor cells. Although the ferricinium cation itself was the most unstable cation
J H Luong et al.
Journal of molecular recognition : JMR, 8(1-2), 132-138 (1995-01-01)
Inclusion complexes of 1,1'-dimethylferrocene (DMFe) with alpha-, 2-hydroxypropyl-beta- or gamma-cyclodextrins were formed in aqueous systems. For the first time, the interacting DMFe-cyclodextrin systems have been characterized using cyclic voltammetry which enabled the estimation of the complexation order, the formation constant
J H Luong et al.
Analytical biochemistry, 212(1), 269-276 (1993-07-01)
Water-soluble 2-hydroxypropyl-beta-cyclodextrin (hp-beta-CyD), a cyclic and nonreducing oligosaccharide, was used to enclose the hydrophobic guest molecules ferrocene (FeCp2) and 1,1'-dimethylferrocene (DMFeCp2) to form a water-soluble complex. At high concentrations (300 mM), hp-beta-CyD enclosed up to 100 mM FeCp2 or DMFeCp2.
D J Claremont et al.
Diabetologia, 29(11), 817-821 (1986-11-01)
Miniature, amperometric glucose sensors were constructed using entrapped 1,1'-dimethylferrocene to mediate electron transfer between immobilised glucose oxidase and a carbon base electrode. Electrodes were calibrated in buffered glucose solutions and then implanted in the subcutaneous tissue of anaesthetised, non-diabetic pigs.
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