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  • A facile synthesis of new 5H-indazolo[3,2-b]benzo[d]-1,3-oxazines via one-pot intramolecular Bis-heterocyclizations.

A facile synthesis of new 5H-indazolo[3,2-b]benzo[d]-1,3-oxazines via one-pot intramolecular Bis-heterocyclizations.

The Journal of organic chemistry (2007-12-07)
Jeffrey D Butler, Danielle M Solano, Lori I Robins, Makhluf J Haddadin, Mark J Kurth
ABSTRACT

The parent 5H-indazolo[3,2-b]benzo[d]-1,3-oxazine heterocycle as well as a series of novel analogues have been synthesized utilizing two subsequent intramolecular heterocyclizations in one pot. A variety of diversity groups were added to explore the scope of this reaction and to provide a number of new compounds for biological screening.

MATERIALS
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Sigma-Aldrich
4-Bromomethyl-3-nitrobenzoic acid, 97%