389560

Phenylphosphonic dichloride

technical grade, 90%

• Synonym(s): Benzenephosphonic dichloride, Benzenephosphonyl chloride, Phenyldichlorophosphine oxide, Phenylphosphonyl dichloride, Phenylphosphoryl dichloride, P,P-Dichlorophenylphosphine oxide
• Linear Formula: C₆H₅POCl₂
• CAS Number: 824-72-6
• Molecular Weight: 194.98
• Beilstein: 1072240
• EC Number: 212-534-3
• MDL number: MFCD00002070
• UNSPSC Code: 12352106
• PubChem Substance ID: 24864291
• NACRES: NA.22

Properties

• grade: technical grade
• Assay: 90%
• form: liquid
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• refractive index: n20/D 1.559 (lit.)
• bp: 258 °C (lit.)
• mp: 3 °C (lit.)
• density: 1.375 g/mL at 25 °C (lit.)
• SMILES string: ClP(Cl)(=O)c1ccccc1
• InChI: 1S/C6H5Cl2OP/c7-10(8,9)6-4-2-1-3-5-6/h1-5H
• InChI key: IBDMRHDXAQZJAP-UHFFFAOYSA-N

Description

Application

Phenylphosphonic dichloride (PPDC) is an organophosphorus compound with flame-retardant properties.
It can be used:

• In the synthesis of PBPP (3,9-diphenyl-3,9-dioxa-2,4,8,10-tetraoxa-3,9-diphosphaspiro-5,5-undecane), another organo-phosphorus flame retardant.
• As a reactant in the synthesis of perfluoroalkyl(phenyl)phosphinic acids from perfluoroalkyl Grignard reagents.
• As a starting material for the synthesis of benzoxazine monomer containing phenylphosphine oxide which can be polymerized via ring-opening polymerization.
• As a chlorinating agent for the conversion of thienopyrimidinedione into 4,6-dichlorothienopyrimidine.

Safety Information

• Pictograms: GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H302,H314,H335
• Precautionary Statements: P261 - P271 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• Target Organs: Respiratory system
• Supplementary Hazards: EUH014
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point(F): 399.2 °F
• Flash Point(C): 204 °C
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves