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115738

Sigma-Aldrich

4-Amino-2,2,6,6-tetramethylpiperidine

98%

Synonym(s):

Triacetonediamine

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About This Item

Empirical Formula (Hill Notation):
C9H20N2
CAS Number:
36768-62-4
Molecular Weight:
156.27
Beilstein:
105038
EC Number:
253-197-2
MDL number:
MFCD00005984
UNSPSC Code:
12352100
PubChem Substance ID:
24847235
NACRES:
NA.22

Quality Level

100

Assay

98%

refractive index

n20/D 1.470 (lit.)

bp

188-189 °C (lit.)

mp

16-18 °C (lit.)

density

0.912 g/mL at 25 °C (lit.)

SMILES string

CC1(C)CC(N)CC(C)(C)N1

InChI

1S/C9H20N2/c1-8(2)5-7(10)6-9(3,4)11-8/h7,11H,5-6,10H2,1-4H3

InChI key

FTVFPPFZRRKJIH-UHFFFAOYSA-N

Gene Information

rat ... Grin2a(24409)

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Application

Additive for light and heat stability of polyamide 6 containing hindered piperidine amines and tertiary amines

Template for preparation of ammoniopiperidinium hydrogen phosphates

Fiber-reactive yellowing inhibitor for partial brightness stabilization of peroxide-bleached pulps

Reactant for thermostability of soybean / sunflower oils

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H290,H302,H314,H412

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Met. Corr. 1 - Skin Corr. 1C

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 2

Flash Point(F)

167.0 °F - closed cup

Flash Point(C)

75 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Haiping Li et al.
Journal of colloid and interface science, 555, 72-81 (2019-08-04)
Construction of Z-scheme heterojunction (ZCH) is one of the most effective ways to enhance photocatalytic performance of photocatalysts. The direct all-solid-state p-n ZCH shows the best prospect, but its fabrication mechanism, especially function of the interfacial electric field (IEF) was
Danielle França de Oliveira et al.
Water science and technology : a journal of the International Association on Water Pollution Research, 76(11-12), 3441-3451 (2017-12-14)
In this study β-zeolite, ferrierite and partially delaminated PREFER (precursor of ferrierite) zeolites with several chemical and textural properties were synthesized for the removal of zinc and lead ion metals from their respective solutions. Adsorption experiments involving the suspension of
Junfeng Zhu et al.
Polymers, 11(12) (2019-12-18)
A novel nitroxyl radical polymer poly(TEMPO-acrylamide-co-sodium styrene sulfonate) (abbreviated as poly(TAm-co-SSS)) was synthesized using 4-acrylamido-2,2,6,6- tetramethylpiperidine (AATP) copolymerized with styrene sulfonate sodium (SSS). AATP was synthesized through a substitution reaction of acryloyl chloride. Meanwhile, poly(4-acrylamido-2,2,6,6-tetramethylpiperidine-1-nitroxyl radical) (PTAm) was prepared as
[Comparative characteristics of the toxicity, safety and nature of the biological effect on the body of 4-hydroxy-2,2,6,6-tetramethylpiperidine and 4-amino-2,2,6,6-tetramethylpiperidine].
A L Germanova et al.
Gigiena truda i professional'nye zabolevaniia, (5)(5), 53-54 (1984-05-01)
Michael A Mercadante et al.
Nature protocols, 8(4), 666-676 (2013-03-09)
We describe the synthesis of the lesser-known stoichiometric oxidation reagent 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate (1, Bobbitt's salt), as well as of 4-acetamido-(2,2,6,6-tetramethyl-piperidin-1-yl)oxyl (2, AcNH-TEMPO). Several representative oxidation reactions are also presented to demonstrate the salt's oxidative capabilities. Bobbitt's salt has a range

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