- Sulfonium boranes for the selective capture of cyanide ions in water.
Sulfonium boranes for the selective capture of cyanide ions in water.
Angewandte Chemie (International ed. in English) (2009-06-06)
Youngmin Kim, Haiyan Zhao, François P Gabbaï
PMID19496090
ABSTRACT
Going fishing! The sulfonium borane [1](+) complexes cyanide in pure water at the maximum allowable concentration of 50 ppb recommended by the European Union. The high cyanide ion affinity displayed by this compound arises from favorable Coulombic effects augmented by a direct bonding interaction between the cyano and sulfonio groups.
MATERIALS