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A96606

Sigma-Aldrich

Azodicarboxamide

97%

Synonym(s):

1,1′-Azobis[formamide], 1,1′-Azobiscarbamide, 1,1′-Azodiformamide, Diazenedicarboxamide (9CI)

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About This Item

Linear Formula:
NH2CON=NCONH2
CAS Number:
123-77-3
Molecular Weight:
116.08
Beilstein:
1704003
EC Number:
204-650-8
MDL number:
MFCD00007958
UNSPSC Code:
12352100
PubChem Substance ID:
24891486
NACRES:
NA.22

Quality Level

100

Assay

97%

form

powder

mp

220-225 °C (dec.) (lit.)

solubility

water: soluble 0.033 g/L at 20 °C

SMILES string

NC(=O)\N=N\C(N)=O

InChI

1S/C2H4N4O2/c3-1(7)5-6-2(4)8/h(H2,3,7)(H2,4,8)/b6-5+

InChI key

XOZUGNYVDXMRKW-AATRIKPKSA-N

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Pictograms

Health hazard
GHS08

Signal Word

Danger

Hazard Statements

H334

Precautionary Statements

P261 - P284 - P501

Hazard Classifications

Resp. Sens. 1

Supplementary Hazards

EUH044

Storage Class Code

4.1A - Other explosive hazardous materials

WGK

WGK 1

Flash Point(F)

>392.0 °F

Flash Point(C)

> 200 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Fourier transform infrared spectrometry (FTIR) for qualitative and quantitative analysis of azodicarboxamide and its potential impurities.
Otte X, et al.
Analytica Chimica Acta, 355(1), 7-13 (1997)
Fourier transform infrared spectrometry (FTIR) for qualitative and quantitative analysis of azodicarboxamide and its potential impurities.
Otte X, et al.
Analytica Chimica Acta, 355(1), 7-13 (1997)
José Berná et al.
Journal of the American Chemical Society, 132(31), 10741-10747 (2010-08-05)
Azodicarboxamides (R(2)NCON=NCONR(2)) are shown to act as new templates for the assembly of unprecedented azo-functionalized hydrogen-bond-assembled [2]rotaxanes. Moreover, these binding sites can be reversibly and efficiently interconverted with their hydrazo forms through a hydrogenation-dehydrogenation strategy of the nitrogen-nitrogen bond. This
Catalytic oxidation of hydrazodicarboxamide to azodicarboxamide by oxygen.
Kaszonyi A, et al.
J. Mol. Catal., 80(3), L13-L17 (1993)
P P J Mulder et al.
Analytica chimica acta, 586(1-2), 366-373 (2007-03-28)
Recently doubts have arisen on the usefulness of semicarbazide as marker residue for the illegal use of the antibiotic nitrofurazone (NFZ) in aquaculture and poultry production. Most notably azodicarbonamide (ADC) has been implicated as an alternative source of semicarbazide. ADC
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