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260916

Sigma-Aldrich

Ethylenebis(triphenylphosphine)platinum(0)

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About This Item

Linear Formula:
[(C6H5)3P]2Pt(H2C=CH2)
CAS Number:
12120-15-9
Molecular Weight:
747.70
MDL number:
MFCD00012028
UNSPSC Code:
12161600
PubChem Substance ID:
24855778
NACRES:
NA.22

reaction suitability

core: platinum
reagent type: catalyst

mp

129-132 °C (dec.) (lit.)

SMILES string

[Pt].C=C.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

InChI

1S/2C18H15P.C2H4.Pt/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;/h2*1-15H;1-2H2;

InChI key

RZUASTIKPBCXPU-UHFFFAOYSA-N

Application

Nucleophilic metal species for ligand exchangewith alkenes and alkynes; catalysts for hydrosilation; reagent for oxidative addition to activated C-X bonds

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Kurosawa, H.; Ogoshi, S. et al.
Journal of the American Chemical Society, 112, 2813-2813 (1990)
Gevorgyan, V.; Borisova, L. et al.
Journal of Organometallic Chemistry, 424, 15-15 (1992)
Uchimaru,Y.; Brandl, P.; Tanaka, M.; Goto, M.
Journal of the Chemical Society. Chemical Communications, 744-744 (1993)

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