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89744

Sigma-Aldrich

Trihexyltetradecylphosphonium chloride

≥95.0% (NMR)

Synonym(s):

Tetradecyltrihexylphosphonium chloride

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About This Item

Linear Formula:
[CH3(CH2)5]3P(Cl)(CH2)13CH3
CAS Number:
Molecular Weight:
519.31
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

≥95.0% (NMR)

form

liquid

density

0.895 g/mL at 20 °C (lit.)

SMILES string

[Cl-].CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC

InChI

1S/C32H68P.ClH/c1-5-9-13-17-18-19-20-21-22-23-24-28-32-33(29-25-14-10-6-2,30-26-15-11-7-3)31-27-16-12-8-4;/h5-32H2,1-4H3;1H/q+1;/p-1

InChI key

JCQGIZYNVAZYOH-UHFFFAOYSA-M

Related Categories

General description

Trihexyltetradecylphosphonium chloride is a hydrophobic ionic liquid, which is soluble in carbon dioxide.

Application

Trihexyltetradecylphosphonium chloride can be used as binder to develop a silver particle-modified carbon paste electrode, which can determine nitrite ions at low concentration.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

244.4 °F

Flash Point(C)

118 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Nickel (II) and cobalt (II) extraction from chloride solutions with quaternary phosphonium salts
Rybka, Patrycja, and Magdalena Regel-Rosocka
Separation Science and Technology, 47.9, 1296-1302 (2012)
Density, viscosity and excess properties in the trihexyltetradecylphosphonium chloride ionic liquid/methanol cosolvent system
McAtee, Zachery P., and Mark P. Heitz
The Journal of Chemical Thermodynamics, 93, 34-44 (2016)
Silver particle-decorated carbon paste electrode based on ionic liquid for improved determination of nitrite
Menart E, et al.
Electrochemical Communications, 52, 45-48 (2015)
Surprisingly high solubility of the ionic liquid trihexyltetradecylphosphonium chloride in dense carbon dioxide.
Hutchings JW, et al.
Green Chemistry, 7(6), 475-478 (2005)
Pan Sun et al.
Journal of colloid and interface science, 539, 214-222 (2018-12-24)
Separation and recycling of rare-earths using ionic liquids as extractant are becoming a promising approach to replace traditional volatile organic solvents in recent years. Generally, the addition of some special salts could improve the extraction efficiency of rare-earths by numerous

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