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683353

Sigma-Aldrich

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)

greener alternative

Synonym(s):

(1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium, Bis(2-methallyl)(1,5-cyclooctadiene)ruthenium, Ru(Me-allyl)2(COD), Ruthenium(II) bis(2-methylallyl) 1,5-cyclooctadiene complex

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About This Item

Linear Formula:
Ru(methylallyl)2(COD)
CAS Number:
12289-94-0
Molecular Weight:
319.45
MDL number:
MFCD00216965
UNSPSC Code:
12352300
PubChem Substance ID:
329760814
NACRES:
NA.22

form

powder

reaction suitability

core: ruthenium
reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

81.7-82.4 °C (lit.)

greener alternative category

, Aligned

storage temp.

−20°C

SMILES string

C1CC=CCCC=C1.CC(=C)C[Ru]CC(C)=C

InChI

1S/C8H12.2C4H7.Ru/c1-2-4-6-8-7-5-3-1;2*1-4(2)3;/h1-2,7-8H,3-6H2;2*1-2H2,3H3;/b2-1-,8-7-;;;

InChI key

GRYFGFSAXGLJLN-PHFPKPIQSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Catalyst for greener amine synthesis by hydrogenation of nitriles.

A Practical and Benign Synthesis of Primary Amines through Ruthenium-Catalyzed Reduction of Nitriles

Legal Information

A product of Umicore

pictograms

Flame
GHS02

signalword

Warning

hcodes

H261

Hazard Classifications

Water-react 3

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 3

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCBW4486
BCBV2422
BCBR3514V
MKBT3795V
MKBQ8356V

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Tuğçe Ayvalı et al.
Dalton transactions (Cambridge, England : 2003), 46(43), 15070-15079 (2017-10-27)
The choice of suitable organometallic precursors, [Re

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