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09682

Sigma-Aldrich

Ammonia

puriss., anhydrous, ≥99.95%

Synonym(s):

Ammonia gas

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About This Item

Linear Formula:
NH3
CAS Number:
7664-41-7
Molecular Weight:
17.03
Beilstein/REAXYS Number:
3587154
EC Number:
231-635-3
MDL number:
MFCD00011418
UNSPSC Code:
12142100
PubChem Substance ID:
329748795
NACRES:
NA.22
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vapor density

0.6 (vs air)

Quality Level

100

vapor pressure

8.75 atm ( 21 °C)

grade

puriss.

assay

≥99.95%

autoignition temp.

1203 °F

expl. lim.

25 %

impurities

≤0.01% water

bp

−33 °C (lit.)

mp

−78 °C (lit.)

SMILES string

N

InChI

1S/H3N/h1H3

InChI key

QGZKDVFQNNGYKY-UHFFFAOYSA-N

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Application

Ammonia gas is a common reagent or reactant in the synthesis of variety of nitrogen containing inorganic compounds and organic intermediates. It is either used directly in gas phase reaction or bubbled through the reaction mixture.[1]
  • Ammonia can be used in the direct synthesis of primary amines from alcohols.[2]
  • Synthesis of N-doped graphene by vapor deposition in the presence of ammonia gas has been reported.[3][4]

Packaging

Cylinder with net ~1 kg

Other Notes

Sales restrictions may apply

Recommended products

Recommended DIN 477 - Nr. 6

replaced by

Product No.
Description
Pricing

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Gas 2 - Press. Gas Liquefied gas - Skin Corr. 1B

supp_hazards

EUH071

Storage Class

2A - Gases

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
STBL4612
STBL3926
STBL3874
STBL3547
STBL3122

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Selective synthesis of primary amines directly from alcohols and ammonia.
Gunanathan C and Milstein D
Angewandte Chemie (International Edition in English), 47(45), 8661-8664 (2008)
Ammonia.
Ullmann's Encyclopedia of Industrial Chemistry (2006)
Synthesis of N-doped graphene by chemical vapor deposition and its electrical properties.
Wei D, et al.
Nano Letters, 9(5), 1752-1758 (2009)
Liangti Qu et al.
ACS nano, 4(3), 1321-1326 (2010-02-17)
Nitrogen-doped graphene (N-graphene) was synthesized by chemical vapor deposition of methane in the presence of ammonia. The resultant N-graphene was demonstrated to act as a metal-free electrode with a much better electrocatalytic activity, long-term operation stability, and tolerance to crossover
Patrick M Erwin et al.
The ISME journal, 8(3), 575-588 (2013-10-25)
Ascidians are ecologically important components of marine ecosystems yet the ascidian microbiota remains largely unexplored beyond a few model species. We used 16S rRNA gene tag pyrosequencing to provide a comprehensive characterization of microbial symbionts in the tunic of 42
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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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