51269
Dihydroxyacetone phosphate hemimagnesium salt hydrate
≥95% (TLC)
Synonym(s):
1,3-Dihydroxy-2-propanone 1-phosphate hemimagnesium salt hydrate, 1-Hydroxy-3-(phosphonooxy)-2-propanone hemimagnesium salt hydrate, DHAP Mg
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About This Item
Empirical Formula (Hill Notation):
C3H5Mg0.5O6P · xH2O
CAS Number:
Molecular Weight:
180.19 (anhydrous basis)
MDL number:
UNSPSC Code:
12352107
PubChem Substance ID:
NACRES:
NA.25
Pricing and availability is not currently available.
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Quality Level
assay
≥95% (TLC)
storage temp.
−20°C
SMILES string
O.OCC(=O)COP(O)(=O)O[Mg]OP(O)(=O)OCC(=O)CO
InChI
1S/2C3H7O6P.Mg.H2O/c2*4-1-3(5)2-9-10(6,7)8;;/h2*4H,1-2H2,(H2,6,7,8);;1H2/q;;+2;/p-2
InChI key
XIBMKSGIYJARCI-UHFFFAOYSA-L
Application
Dihydroxyacetone phosphate hemimagnesium salt hydrate (DHAP Mg) is a magnesium salt of DHAP. DHAP may be used as the substrate to characterize enzymes such as fructose bisphosphate aldolase and triose phosphate isomerase.
Biochem/physiol Actions
Dihydroxyacetone phosphate (DHAP) is a metabolic intermediate involved in many pathways, including glycolysis, gluconeogenesis, glycerol metabolism, phosphatidic acid synthesis, fat metabolism, and the Calvin cycle.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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An efficient gram scale synthesis of 3-fluoro-1-hydroxyacetone phosphate (FHAP) has been developed. As a close analog to dihydroxyacetone phosphate, FHAP was used as a novel donor substrate for rabbit muscle aldolase catalyzed reactions. The different binding affinities of the gem-diol
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Aldol addition reactions of dihydroxyacetone (DHA) to N-Cbz-amino aldehydes catalyzed by L-rhamnulose-1-phosphate aldolase (RhuA) in the presence of borate buffer are reported. High yields of aldol adduct (e.g. 70-90%) were achieved with excellent (>98 : 2 syn/anti) stereoselectivity for most S or
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