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Sigma-Aldrich

Hydrazine

anhydrous, 98%

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$143.00
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$250.00

$143.00

Estimated to ship onJanuary 28, 2025Details

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50 G
$143.00
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About This Item

Linear Formula:
NH2NH2
CAS Number:
302-01-2
Molecular Weight:
32.05
EC Number:
206-114-9
MDL number:
MFCD00011417
UNSPSC Code:
12352300
PubChem Substance ID:
24852873
NACRES:
NA.21
assay:
98%
grade:
anhydrous
form:
liquid

$143.00

Estimated to ship onJanuary 28, 2025Details

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grade

anhydrous

Quality Level

200

vapor density

1 (37 °C, vs air)

vapor pressure

10 mmHg ( 30.7 °C)

assay

98%

form

liquid

expl. lim.

99.99 %

refractive index

n20/D 1.47 (lit.)

bp

113.5 °C (lit.)

mp

1.4 °C (lit.)

density

1.021 g/mL at 25 °C (lit.)

SMILES string

NN

InChI

1S/H4N2/c1-2/h1-2H2

InChI key

OAKJQQAXSVQMHS-UHFFFAOYSA-N

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General description

Hydrazine is the simplest diamine[1] mainly used as a reducing agent.[2]
Sensitive determination of hydrazine with detection limit of 10.0nM has been achieved by employing an electrochemical sensor.[3] Hydrazine undergoes dehydrogenation in the presence of bimetallic NiRh nanoparticles (NPs) supported on nitrogen-doped porous carbon (NPC) derived from metal-organic frameworks (ZIF-8) to afford hydrogen.[4]

Application

Hydrazine has been used as one of the reaction components in the synthesis of a soluble chalcogenidometallate cluster salt, which is a precursor for the preparation of SnSe2.[5]
Hydrazine may be used in the synthesis of:
  • pyridyl aminated O-linked sugar chains from glycoproteins[6]
  • nanocomposite of manganese oxide embedded in graphene sheets (GS–Mn3O4)[7]
  • formyl hydrazine by reacting with ethyl formate[8]

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signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

100.4 °F - closed cup

flash_point_c

38 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX0129
MKCW7234
MKCV1555
MKCT8648
MKCV4940

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Buse Demirkan et al.
Journal of colloid and interface science, 552, 432-438 (2019-06-04)
In this study, a facile ex situ synthesis of a polyaniline-multiwalled carbon nanotube-based Pt nanocatalyst (Pt@PANI-MWCNT) with an average particle size of 3.18 ± 0.12 nm was performed successfully. The obtained Pt@PANI-MWCNT nanocatalysts were isolated from the solution medium by centrifugation and then
Rapid microwave-assisted synthesis of Mn 3 O 4?graphene nanocomposite and its lithium storage properties
Li L, et al.
Journal of Materials Chemistry, 22(8), 3600-3605 (2012)
Yoriko Nonomura et al.
Scientific reports, 9(1), 1551-1551 (2019-02-09)
Membrane proteins (such as ion channels, transporters, and receptors) and secreted proteins are essential for cellular activities. N-linked glycosylation is involved in stability and function of these proteins and occurs at Asn residues. In several organs, profiles of N-glycans have
Hadi Mahmoudi Moghaddam et al.
Environmental monitoring and assessment, 187(7), 407-407 (2015-06-06)
Hydrazine and phenol are two important environmental pollutants. In this work, an electrochemical sensor for the selective and sensitive detection of hydrazine in presence of phenol was developed by the bulk modification of carbon paste electrode (CPE) with TiO2 nanoparticles
Release of O-linked sugar chains from glycoproteins with anhydrous hydrazine and pyridylamination of the sugar chains with improved reaction conditions.
Kuraya N and Hase S.
Journal of Biochemistry, 112(1), 122-126 (1992)
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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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