667552
1-Acetyl-1H-benzotriazole
97%
Synonym(s):
1-Acetylbenzotriazole
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assay
97%
form
solid
reaction suitability
reaction type: C-C Bond Formation
mp
46-50 °C
SMILES string
CC(=O)n1nnc2ccccc12
InChI
1S/C8H7N3O/c1-6(12)11-8-5-3-2-4-7(8)9-10-11/h2-5H,1H3
InChI key
NIIUIBKEGRPPDK-UHFFFAOYSA-N
Application
1-Acetyl-1H-benzotriazole can be used as a reactant for the preparation of:
- 1-aryl-1H-1,2,3-benzotriazoles by reacting with diaryliodonium salts via C-N activation reaction.
- N-substituted-2-((1- and 2-benzotriazolyl)methyl)-3-acrylates by treating with Baylis-Hillman acetate in the presence of K2CO3.
- Thioacids and thioamino acids by thiolysis in presence of sodium hydrosulfide (NaSH) in water.
Reactant for:
- Preparation of N-acyl imidazolidinones by acylation of imidazolidinone, in the presence of K2CO3
- Acylation of cellulose in DMSO/tetrabutylammonium fluoride trihydrate
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Stereoselective and regioselective synthesis of N-substituted methyl 2-((azolyl) methyl)-3-arylacrylates from Baylis-Hillman acetates
Turkish Journal of Chemistry, 41(3), 323-334 (2017)
Catalyst-and organic solvent-free synthesis of thioacids in water
Tetrahedron Letters, 60(30), 2018-2021 (2019)
Cu-catalyzed arylation of 1-acyl-1H-1, 2, 3-Benzotriazoles via C-N activation
Journal of Organometallic Chemistry, 895, 64-67 (2019)
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