Skip to Content
MilliporeSigma
All Photos(1)

Key Documents

View All Documentation

540390

Sigma-Aldrich

(3,4-Dihydro-1-naphthyloxy)trimethylsilane

97%

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C13H18OSi
CAS Number:
38858-72-9
Molecular Weight:
218.37
MDL number:
MFCD03093969
UNSPSC Code:
12352100
PubChem Substance ID:
24878464
NACRES:
NA.22

Quality Level

100

assay

97%

refractive index

n20/D 1.5287 (lit.)

bp

63-65 °C/0.01 mmHg (lit.)

density

0.983 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(C)OC1=CCCc2ccccc12

InChI

1S/C13H18OSi/c1-15(2,3)14-13-10-6-8-11-7-4-5-9-12(11)13/h4-5,7,9-10H,6,8H2,1-3H3

InChI key

CAUIWDWUUCGKBV-UHFFFAOYSA-N

General description

(3,4-Dihydro-1-naphthyloxy)trimethylsilane (3,4-dihydronaphthalen-1-yloxy(trimethyl)silane) is a protected phenol. Its IR spectral analysis suggests νmax (DCM) = 1638cm-1.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

William J Kerr et al.
Chemical communications (Cambridge, England), (47)(47), 5049-5051 (2007-12-01)
Bismesitylmagnesium has been established as an accessible, practical, convenient, and non-nucleophilic carbon-centred base reagent for efficient access to silyl enol ethers from a series of ketone substrates at readily utilisable temperatures.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service