520268
4,4′,4″-Tri-tert-Butyl-2,2′:6′,2″-terpyridine
95%
Synonym(s):
2,6-Bis[4-(tert-butyl)pyridin-2-yl)-4-(tert-butyl)pyridine
About This Item
Recommended Products
assay
95%
impurities
oligomers of tert-butyl-terpyridine
mp
215-217 °C (lit.)
SMILES string
CC(C)(C)c1ccnc(c1)-c2cc(cc(n2)-c3cc(ccn3)C(C)(C)C)C(C)(C)C
InChI
1S/C27H35N3/c1-25(2,3)18-10-12-28-21(14-18)23-16-20(27(7,8)9)17-24(30-23)22-15-19(11-13-29-22)26(4,5)6/h10-17H,1-9H3
InChI key
QMABMHJGSFUTPF-UHFFFAOYSA-N
Application
- In the synthesis of methylated alkanes and ketones via Ni-catalyzed methylation of unactivated alkyl halides and acid chlorides.
- In Ni-catalyzed reductive dimerization reaction.
- In allylic defluorinative reductive cross-coupling reaction in the presence of Ni as a catalyst.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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