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456411

Sigma-Aldrich

Titanium(III) chloride-aluminum chloride

TiCl3:AlCl3 3:1

Synonym(s):

Aluminum titanium chloride

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About This Item

Linear Formula:
(TiCl3)3 · AlCl3
CAS Number:
12003-13-3
Molecular Weight:
596.02
EC Number:
234-421-8
MDL number:
MFCD00083104
UNSPSC Code:
12352106
PubChem Substance ID:
24869176

form

solid

composition

TiCl3:AlCl3, 3:1

reaction suitability

reagent type: catalyst
core: titanium

SMILES string

Cl[Al](Cl)Cl.Cl[Ti](Cl)Cl.Cl[Ti](Cl)Cl.Cl[Ti](Cl)Cl

InChI

1S/Al.12ClH.3Ti/h;12*1H;;;/q+3;;;;;;;;;;;;;3*+3/p-12

InChI key

DGFMFXMKCUOBCD-UHFFFAOYSA-B

Application

Low-valent titanium is a useful reducing agent in the synthesis of imidazolines.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Pyr. Sol. 1 - Skin Corr. 1B

supp_hazards

EUH014

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
07421TH
11820DD
14029CO
10403HA
05517DR

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Periasamy, M. et al.
Tetrahedron Letters, 37, 4767-4767 (1996)

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