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437093

Sigma-Aldrich

[Bis(trimethylsilyl)acetylene](hexafluoroacetylacetonato)copper(I)

Synonym(s):

[(η2-1,2-Ethynediyl)bis[trimethylsilane]](1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-O,O′) copper

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About This Item

Linear Formula:
(CH3)3SiC≡CSi(CH3)3·[CF3COCH=C(O-)CF3]Cu
CAS Number:
Molecular Weight:
441.00
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

form

solid

reaction suitability

core: copper
reagent type: catalyst

mp

51-54 °C (lit.)

storage temp.

2-8°C

SMILES string

C[Si](C)(C)C#C[Si](C)(C)C.FC(F)(F)C(=O)\C=C(\O[Cu])C(F)(F)F

InChI

1S/C8H18Si2.C5H2F6O2.Cu/c1-9(2,3)7-8-10(4,5)6;6-4(7,8)2(12)1-3(13)5(9,10)11;/h1-6H3;1,12H;/q;;+1/p-1/b;2-1+;

InChI key

YESCMKQKTNVQCY-JITBQSAISA-M

Application

Investigations of the structure and fluorescence of copper hexafluoropentanedionate alkyne clusters

Used in chemical vapor depositing of copper
Used in chemical vapor deposition of copper.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

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Mrs Bulletin, 19, 41-41 (1994)
Journal of the Electrochemical Society, 140, 154-154 (1993)
Materials Research Society Symposia Proceedings. Materials Research Society, 260, 629-629 (1992)

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