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362174

Sigma-Aldrich

(Bicyclo[2.2.1]hepta-2,5-diene)dichloropalladium(II)

98%

Synonym(s):

Dichloro (norbornadiene)palladium(II), NSC 176915, PdCl2(nbd)

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About This Item

Empirical Formula (Hill Notation):
C7H8Cl2Pd
CAS Number:
12317-46-3
Molecular Weight:
269.46
EC Number:
235-583-2
MDL number:
MFCD00134222
UNSPSC Code:
12352300
PubChem Substance ID:
24862295
NACRES:
NA.22

assay

98%

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

260 °C (dec.) (lit.)

SMILES string

Cl[Pd]Cl.[CH]1[CH]C2[CH][CH]C1C2

InChI

1S/C7H8.2ClH.Pd/c1-2-7-4-3-6(1)5-7;;;/h1-4,6-7H,5H2;2*1H;/q;;;+2/p-2

InChI key

BNCRZJHZZCMDNP-UHFFFAOYSA-L

Application

Catalyst for:
  • Aerobic kinetic resolution of secondary alcohols
  • Kinetic oxidative resolution of 1-phenyl ethanol
  • Oxidative kinetic resolution-Claisen rearrangement sequence
  • Aerobic oxidation of secondary alcohols

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKBB5332
04516KC
04920PW

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