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Sigma-Aldrich

Iron(III) perchlorate hydrate

crystalline, low chloride

Synonym(s):

Perchloric acid iron(III) salt hydrate

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About This Item

Linear Formula:
Fe(ClO4)3 · xH2O
CAS Number:
Molecular Weight:
354.20 (anhydrous basis)
EC Number:
MDL number:
UNSPSC Code:
12352000
PubChem Substance ID:
NACRES:
NA.22

form

crystalline

reaction suitability

reagent type: oxidant

impurities

<0.005% chloride

color

pale violet

SMILES string

[Fe+3].[H]O[H].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

InChI

1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3

InChI key

PFPIMAZLJXJVAN-UHFFFAOYSA-K

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Related Categories

Application

Catalyst for synthesis of:
  • Fullerene-fused lactones
  • α-Carbonyl furans via one-pot cyclization
  • Fullerodioxolanes via heterocyclization
  • Dialylated indoles via double alkylation
  • Aryl esters via oxidative esterification

Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution

Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization
Useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units which allow two coordination modes.

pictograms

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Danger

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


Certificates of Analysis (COA)

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Structural Characterization of a Tris-salicylate Coordination for Iron(III) with the Tripodal Ligand O-TRENSOX.
Guy Serratrice et al.
Inorganic chemistry, 38(5), 840-841 (2001-10-24)

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