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194654

Sigma-Aldrich

Chrysanthemyl alcohol, mixture of cis and trans

98%

Synonym(s):

2,2-Dimethyl-3-(2-methylpropenyl)cyclopropanemethanol, Chrysanthemol

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About This Item

Linear Formula:
(CH3)2C3H2[CH=C(CH3)2]CH2OH
CAS Number:
5617-92-5
Molecular Weight:
154.25
EC Number:
227-045-0
MDL number:
MFCD00001305
UNSPSC Code:
12352100
PubChem Substance ID:
24851331

assay

98%

refractive index

n20/D 1.475 (lit.)

bp

66-69 °C/0.07 mmHg (lit.)

density

0.888 g/mL at 25 °C (lit.)

SMILES string

C\C(C)=C\C1C(CO)C1(C)C

InChI

1S/C10H18O/c1-7(2)5-8-9(6-11)10(8,3)4/h5,8-9,11H,6H2,1-4H3

InChI key

HIPIENNKVJCMAP-UHFFFAOYSA-N

General description

Oxidation of chrysanthemyl alcohol in the presence of [RuO4]2- yields chrysantheniic acid[1].

Application

Chrysanthemyl alcohol was used in the determination of position of double bonds in various terepenes and branched chain compounds[2].

pictograms

Environment
GHS09

hcodes

H411

pcodes

P273

Hazard Classifications

Aquatic Chronic 2

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

185.0 °F - closed cup

flash_point_c

85 °C - closed cup

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Certificates of Analysis (COA)

Lot/Batch Number
SHBC9660
77696KM
76796MK
9917KL
09208LR

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L Y Mou et al.
Journal of Asian natural products research, 3(2), 103-116 (2001-06-16)
Chrysanthemol (1), a trans-eudesmane type sesquiterpene from Chrysanthemum indicum L., possesses certain anti-inflammatory activity. Its total synthesis was approached from two alternative routes and finally accomplished in ten steps from R-(+)-carvone via alpha-eudesmol (10) as the key intermediate. The overall
[Studies on the chemical constituents of Chrysanthemum indicum L].
D Q Yu et al.
Yao xue xue bao = Acta pharmaceutica Sinica, 22(11), 837-840 (1987-11-01)
A B Attygalle et al.
Analytical chemistry, 65(18), 2528-2533 (1993-09-15)
The electron-impact mass spectra of alpha, beta-bis(methylthio) derivatives of certain terpenes and other compounds with branched alkenyl groups contain diagnostic peaks that can be used for locating the position of the double bond in the parent compound. In contrast to
Oxo complexes of ruthenium (VI) and (VII) as organic oxidants.
Green G, et al.
Journal of the Chemical Society. Perkin Transactions 1, 681-686 (1984)
Gas chromatographic determination of racemic cis- and trans-chrysanthemols and their potential aldehyde and carboxylic acid microbial metabolites.
M Miski et al.
Journal of chromatography, 437(2), 436-441 (1988-03-25)

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