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60279

Sigma-Aldrich

Potassium hexacyanoferrate(II) trihydrate

BioUltra, ≥99.5% (RT)

Synonym(s):

Potassium ferrocyanide, Yellow prussiate

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About This Item

Linear Formula:
K4Fe(CN)6 · 3H2O
CAS Number:
Molecular Weight:
422.39
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.25

product line

BioUltra

Quality Level

assay

≥99.5% (RT)

form

solid

impurities

insoluble matter, passes filter test

pH

8.0-10.0 (25 °C, 0.5 M in H2O)

mp

70 °C (lit.)

solubility

H2O: 0.5 M at 20 °C, clear, faintly yellow to greenish-yellow

anion traces

carbonate (CO32-): ≤20 mg/kg
chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

As: ≤0.1 mg/kg
Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤10 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Na: ≤100 mg/kg
Ni: ≤5 mg/kg
Pb: ≤10 mg/kg
Sr: ≤5 mg/kg
Zn: ≤10 mg/kg

absorption

cut-off at 411 nm in H2O at 0.5 M

SMILES string

O.O.O.[K+].[K+].[K+].[K+].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N

InChI

1S/6CN.Fe.4K.3H2O/c6*1-2;;;;;;;;/h;;;;;;;;;;;3*1H2/q;;;;;;-4;4*+1;;;

Inchi Key

NRYOVBQTVIWDNU-UHFFFAOYSA-N

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Application

Potassium hexacyanoferrate(II) a redox couple with potassium hexacyanoferrate(III) is used with luminol-based chemiluninescent assays.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Gloves


Certificates of Analysis (COA)

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Jianxiu Du et al.
Luminescence : the journal of biological and chemical luminescence, 17(3), 165-167 (2002-08-08)
A new flow injection chemiluminescence method is described for the determination of captopril. It is based on the enhancing effect of captopril on the chemiluminescence reaction of luminol with potassium ferricyanide in alkaline solution in the presence of potassium ferrocyanide.
Vasiliy N Goral et al.
Lab on a chip, 6(3), 414-421 (2006-03-03)
A microfluidic biosensor with electrochemical detection for the quantification of nucleic acid sequences was developed. In contrast to most microbiosensors that are based on fluorescence for signal generation, it takes advantage of the simplicity and high sensitivity provided by an
Reda R Sheha
Journal of colloid and interface science, 388(1), 21-30 (2012-09-25)
Nanocrystalline potassium zinc hexacyanoferrate loaded on nanoscale magnetite substrate was successfully synthesized for significantly enhanced removal of cesium from low-level radioactive wastes. A description was given for preparation and properties of these precursors. The physicochemical properties of these nanocomposites were
Takeshi Hasegawa et al.
Biomedical chromatography : BMC, 24(6), 613-619 (2009-10-10)
A simple, sensitive and specific chemiluminescent high-performance liquid chromatography method, based on the luminol reaction, for determination of serum cortisol and cortisone, was established. In infants, placental 11beta-hydroxysteroid dehydrogenase type 2 enzyme (11beta-HSD2) activity may affect adrenal function early after
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Laboratory investigation; a journal of technical methods and pathology, 100(1), 84-97 (2019-08-15)
Pancreatic exocrine secretory processes are challenging to investigate on primary epithelial cells. Pancreatic organoid cultures may help to overcome shortcomings of the current models, however the ion secretory processes in pancreatic organoids-and therefore their physiological relevance or their utility in

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