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28-3690

Sigma-Aldrich

Sodium persulfate

SAJ first grade, ≥98.0%

Synonym(s):

Sodium peroxodisulfate

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About This Item

Linear Formula:
Na2S2O8
CAS Number:
7775-27-1
Molecular Weight:
238.10
EC Number:
231-892-1
MDL number:
MFCD00003501
UNSPSC Code:
12352302
PubChem Substance ID:
329753170
assay:
≥98.0%
grade:
SAJ first grade
form:
fine crystals

grade

SAJ first grade

assay

≥98.0%

form

fine crystals

reaction suitability

reagent type: oxidant

availability

available only in Japan

pH

2.5-4.0

SMILES string

[Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O

InChI

1S/2Na.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h;;(H,1,2,3)(H,4,5,6)/q2*+1;/p-2

InChI key

CHQMHPLRPQMAMX-UHFFFAOYSA-L

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Ox. Sol. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1B - Oxidizing hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
U6349
U3150
U3022
U5944
U0852

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Xiaodan Zhao et al.
Journal of the American Chemical Society, 132(16), 5837-5844 (2010-04-03)
By palladium catalysis, the C-H bond functionalization of O-phenylcarbamates with simple arenes has been achieved using sodium persulfate (Na(2)S(2)O(8)), an inexpensive, easy-to-handle, and environmentally friendly oxidant. This oxidative cross-coupling involves two aromatic C-H bonds undergoing concomitant oxidation to furnish a
Chenju Liang et al.
Chemosphere, 70(3), 426-435 (2007-08-19)
In situ chemical oxidation with persulfate anion (S2O82*) is a viable technique for remediation of groundwater contaminants such as trichloroethylene (TCE). An accelerated reaction using S2O82* to destroy TCE can be achieved via chemical activation with ferrous ion to generate
Amy L Teel et al.
Journal of hazardous materials, 196, 153-159 (2011-10-05)
The potential for 13 naturally occurring minerals to mediate the decomposition of persulfate and generate a range of reactive oxygen species was investigated to provide fundamental information on activation mechanisms when persulfate is used for in situ chemical oxidation (ISCO).
Chia-Hsien Yen et al.
Journal of hazardous materials, 186(2-3), 2097-2102 (2011-01-25)
In this study, batch experiments were conducted to evaluate the feasibility of petroleum-hydrocarbon contaminated soil remediation using persulfate oxidation. Various controlling factors including different persulfate and ferrous ion concentrations, different oxidants (persulfate, hydrogen peroxide, and permanganate), and different contaminants (diesel
Zhiguo Zhang et al.
The Journal of organic chemistry, 77(17), 7665-7670 (2012-08-02)
Mediated by sodium persulfate (Na(2)S(2)O(8)), a series of polysubstituted 4-pyridones were synthesized via self-condensation of N-aryl acetoacetamides, during which a novel N to C 1,3-acyl migration should be involved. The structure of 4-pyridone was unequivocally confirmed by X-ray diffraction analysis.
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