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D87759

Sigma-Aldrich

7-Diethylamino-4-methylcoumarin

99%

Synonym(s):

Coumarin 1

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About This Item

Empirical Formula (Hill Notation):
C14H17NO2
CAS Number:
91-44-1
Molecular Weight:
231.29
EC Number:
202-068-9
MDL number:
MFCD00006864
UNSPSC Code:
12352103
PubChem Substance ID:
57654137
NACRES:
NA.23

assay

99%

form

solid

mp

72-75 °C (lit.)

SMILES string

CCN(CC)c1ccc2C(C)=CC(=O)Oc2c1

InChI

1S/C14H17NO2/c1-4-15(5-2)11-6-7-12-10(3)8-14(16)17-13(12)9-11/h6-9H,4-5H2,1-3H3

InChI key

AFYCEAFSNDLKSX-UHFFFAOYSA-N

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General description

7-Diethylamino-4-methylcoumarin (C1) is a bichromophoric fluorescent laser dye, which has a laser action at 460 nm.

Application

Terbium based metal organic framework may be doped with C1 for potential use in ratiometric temperature sensing. C1 may also be used as a fluorescent photo-initiator that can act as an optical brightener for use in the synthesis of the light emitting diode (LED) based hydrogel.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Origin of the dual-band laser emission from 7-diethylamino-4-methylcoumarin (C1) in solution: effect of hydrogen-bonding interaction by hydroxylic molecules
Yip RW and Wen YX
Canadian Journal of Chemistry, 69(9), 1413-1417 (1991)
Vishakha R Shembekar et al.
Biochemistry, 44(19), 7107-7114 (2005-05-11)
We report on a photolabile protecting (caging) group that is new for carboxylic acids. Unlike previously used caging groups for carboxylic acids, it can be photolyzed rapidly and efficiently in the visible wavelength region. The caging group 7-N,N-diethyl aminocoumarin (DECM)
M A Saleh et al.
Chemosphere, 36(7), 1543-1552 (1998-03-21)
Six different types of fabrics were compared for their ability to protect against human exposure to three different commercial household aerosol insecticides. Fabrics used in this investigation were, 100% cotton, cotton-polyester thermal underwear, cotton-polyester blend (twill), 100% acrylic, 100% wool
Visual scoring system for fluorescent tracer evaluation of dermal exposure to pesticides.
R A Fenske
Bulletin of environmental contamination and toxicology, 41(5), 727-736 (1988-11-01)
Novel applications of fluorescent brighteners in aqueous visible-light photopolymerization: high performance water-based coating and LED-assisted hydrogel synthesis
Zuo X, et al.
Polym. Chem., 9(28), 3952-3958 (2018)
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