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D32202

Sigma-Aldrich

Dibenzothiophene

98%

Synonym(s):

DBT, Diphenylene sulfide

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$61.80
100 G
$235.00
250 G
$334.00

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25 G
$61.80
100 G
$235.00
250 G
$334.00

About This Item

Empirical Formula (Hill Notation):
C12H8S
CAS Number:
Molecular Weight:
184.26
Beilstein/REAXYS Number:
121101
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

$61.80


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Quality Level

assay

98%

form

powder or crystals

bp

332-333 °C (lit.)

mp

97-100 °C (lit.)

SMILES string

c1ccc2c(c1)sc3ccccc23

InChI

1S/C12H8S/c1-3-7-11-9(5-1)10-6-2-4-8-12(10)13-11/h1-8H

InChI key

IYYZUPMFVPLQIF-UHFFFAOYSA-N

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Application

Dibenzothiophene (DBT) can be used as:
  • A starting material for the synthesis of corresponding sulfoxide and sulfone by oxidative desulfurization using various catalysts.[1][2][3]
  • A template for the synthesis of surface molecular imprinted polymer (SMIP). SMIP is applicable for the removal of dibenzothiophene during desulfurization of the gasoline[4]
  • A precursor for the synthesis of DBT based π-conjugating polymers.[5]

pictograms

Exclamation markEnvironment

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

338.0 °F

flash_point_c

170 °C

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Olga Senko et al.
Molecules (Basel, Switzerland), 24(9) (2019-05-08)
Sulfur recovery from organic molecules such as toxic sulfones is an actual problem, and its solution through the use of environmentally friendly and nature-like processes looks attractive for research and application. For the first time, the possible bioconversion of organic
Oxidative desulfurization of dibenzothiophene and diesel over [Bmim]3PMo12O40
Zhang J, et al.
J. Catal., 279(2), 269-275 (2011)
Hydrodesulfurization of dibenzothiophene and 4, 6-dimethyldibenzothiophene over sulfided NiMo/γ-Al2O3, CoMo/γ-Al2O3, and Mo/γ-Al2O3 catalysts
Egorova, Marina and Prins, Roel
J. Catal., 225(2), 417-427 (2004)
Synthesis of novel π-conjugating polymers based on dibenzothiophene
Nemoto N, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 41(10), 1521-1526 (2003)
Hydrodesulfurization of dibenzothiophene over siliceous MCM-41-supported nickel phosphide catalysts
Wang, A, et al.
J. Catal., 229(2), 314-321 (2005)

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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