If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
A30702
Allyl chloride
reagent grade, 98%
Synonym(s):
3-Chloro-1-propene, Chlorallylene
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About This Item
Recommended Products
grade
reagent grade
Quality Level
vapor density
2.6 (vs air)
vapor pressure
20.58 psi ( 55 °C)
5.71 psi ( 20 °C)
assay
98%
form
liquid
expl. lim.
11.2 %
refractive index
n20/D 1.414 (lit.)
bp
44-46 °C (lit.)
mp
−130 °C (lit.)
density
0.939 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
ClCC=C
InChI
1S/C3H5Cl/c1-2-3-4/h2H,1,3H2
InChI key
OSDWBNJEKMUWAV-UHFFFAOYSA-N
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Application
- 1-Allyl-2-alkynylbenzene derivatives through allylalkynylation of in situ generated benzynes.[1]
- α,ω-Difunctional intermediates by reacting with fatty acid methyl esters using ruthenium catalysts.[2]
- Homoallylic alcohols through Sn/I2 catalyzed Barbier-type allylation reactions of carbonyl compounds.[3]
Other Notes
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
target_organs
Nervous system,Liver,Kidney, Respiratory system
Storage Class
3 - Flammable liquids
wgk_germany
WGK 2
flash_point_f
-25.6 °F
flash_point_c
-32 °C
ppe
Eyeshields, Faceshields, Gloves
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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