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Sigma-Aldrich

Bis[tris(3-(heptadecafluorooctyl)phenyl)phosphine]palladium(II) dichloride

≥95% (31P-NMR)

Synonym(s):

Bis[tris(3-(perfluorooctyl)phenyl)phosphine]palladium(II) dichloride

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About This Item

Empirical Formula (Hill Notation):
C84H24Cl2F102P2Pd
CAS Number:
326475-45-0
Molecular Weight:
3210.20
MDL number:
MFCD03791111
UNSPSC Code:
12352200
PubChem Substance ID:
24889106

assay

≥95% (31P-NMR)

SMILES string

Cl[Pd]Cl.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)c1cccc(c1)P(c2cccc(c2)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)c3cccc(c3)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)c4cccc(c4)P(c5cccc(c5)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)c6cccc(c6)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

Application

Catalyst for Stille and Suzuki couplings in Fluorous Biphase Systems (FBS)

Other Notes

Perfluoro-tagged Pd complexes as catalysts for Stille couplings in a fluorous biphase system, palladium-catalyzed Suzuki couplings.

Certificates of Analysis (COA)

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T. Osswald et al.
Tetrahedron Letters, 42, 2965-2965 (2001)
S. Schneider et al.
Helvetica Chimica Acta, 84, 735-735 (2001)
S. Schneider et al.
Angewandte Chemie (International Edition in English), 112, 4293-4293 (2000)

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