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87749

Sigma-Aldrich

Ethyl 2,2,5,5-tetramethyl-1,2,5-azadisilolidin-1-acetate

≥98.0%

Synonym(s):

(1-Ethoxycarbonylmethyl)-2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopentane, 2,2,5,5-Tetramethyl-1,2,5-azadisilolidin-1-acetic acid ethyl ester, STABASE-ethyl glycinate

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About This Item

Empirical Formula (Hill Notation):
C10H23NO2Si2
CAS Number:
Molecular Weight:
245.47
Beilstein/REAXYS Number:
3545518
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:

assay

≥98.0%

refractive index

n20/D 1.451 (lit.)
n20/D 1.451

bp

80-82 °C/0.25 mmHg (lit.)

density

0.95 g/mL at 25 °C (lit.)

SMILES string

CCOC(=O)CN1[Si](C)(C)CC[Si]1(C)C

InChI

1S/C10H23NO2Si2/c1-6-13-10(12)9-11-14(2,3)7-8-15(11,4)5/h6-9H2,1-5H3

InChI key

NTAZFMGCNVXERO-UHFFFAOYSA-N

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Other Notes

Starting material for the synthesis of various α-amino acids; Cycloaddition of its enolate with imines

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

181.4 °F - closed cup

flash_point_c

83 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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G. Cainelli et al.
Tetrahedron Letters, 28, 5369-5369 (1987)
F.H. van der Steen et al.
Tetrahedron Letters, 29, 2467-2467 (1988)
S. Djuric et al.
Tetrahedron Letters, 22, 1787-1787 (1981)
G. Bold et al.
Angewandte Chemie (International Edition in English), 101, 491-491 (1989)
P.F. Hudrlik et al.
Journal of the American Chemical Society, 103, 6251-6251 (1981)

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