778761

(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine

≥95.0% (HPLC)

• Synonym(s): (S,S)-11,12-Diamino-9,10-dihydro-9,10-ethanoanthracene
• Empirical Formula (Hill Notation): C₁₆H₁₆N₂
• CAS Number: 138517-66-5
• Molecular Weight: 236.31
• Beilstein/REAXYS Number: 8693351
• MDL number: MFCD09038519
• UNSPSC Code: 12352116
• PubChem Substance ID: 329767993
• NACRES: NA.22

Properties

• assay: ≥95.0% (HPLC); 95.0-105.0% (NT)
• form: powder
• optical purity: enantiomeric excess: ≥98.0%
• SMILES string: N[C@H]1[C@H](N)[C@H]2c3ccccc3[C@@H]1c4ccccc24
• InChI: 1S/C16H16N2/c17-15-13-9-5-1-2-6-10(9)14(16(15)18)12-8-4-3-7-11(12)13/h1-8,13-16H,17-18H2/t13-,14+,15-,16-/m1/s1
• InChI key: NWDYSRZJOLDMRE-QKPAOTATSA-N

Description

Application

(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine is a chiral diamine, which can be used as a reactant:

• To synthesize pyridine based C₂-symmetrical chiral organocatalysts via palladium catalyzed coupling reaction with 2-bromo-4-(alkylamino)pyridine.
• To prepare porous organic imine cages by cycloimination reaction with triformylbenzene.
• To synthesize Ga/Yb-Schiff base complex, which is utilized as a catalyst for the asymmetric synthesis of 5-amino-2-(hydroxyalkyl)oxazoles by enantioselective α-addition of α-isocyano amides to aldehydes.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Safety Information

• Storage Class: 13 - Non Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable