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744980

Sigma-Aldrich

1-(Azidomethyl)-2-methylbenzene solution

~0.5 M in tert-butyl methyl ether, ≥97.0% (HPLC)

Synonym(s):

α-Azido-o-xylene solution, o-Methylbenzyl azide solution

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About This Item

Empirical Formula (Hill Notation):
C8H9N3
CAS Number:
126799-83-5
Molecular Weight:
147.18
Beilstein/REAXYS Number:
4860454
MDL number:
MFCD11637152
UNSPSC Code:
12352200
PubChem Substance ID:
329765720
NACRES:
NA.22

assay

≥97.0% (HPLC)

form

liquid

reaction suitability

reaction type: click chemistry

concentration

~0.5 M in tert-butyl methyl ether

impurities

≤2.0% water

storage temp.

2-8°C

SMILES string

Cc1ccccc1CN=[N+]=[N-]

InChI

1S/C8H9N3/c1-7-4-2-3-5-8(7)6-10-11-9/h2-5H,6H2,1H3

InChI key

TWZXVFYNRLIXRY-UHFFFAOYSA-N

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

hcodes

H225,H315

Hazard Classifications

Flam. Liq. 2 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

-18.4 °F

flash_point_c

-28 °C

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Certificates of Analysis (COA)

Lot/Batch Number
BCBG4186V
BCBG4186

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Meina Liu et al.
Organic letters, 13(5), 1102-1105 (2011-02-12)
A structurally well-defined copper(I) isonitrile complex is shown to be an efficient, heterogeneous catalyst for the Huisgen azide-alkyne 1,3-dipolar cycloaddition under mild conditions in water. Notably, this catalyst can also be utilized in a three-component reaction of halides, sodium azide
Atif Sarwar et al.
PloS one, 10(4), e0123084-e0123084 (2015-05-01)
Recently, the attention of researchers has been drawn toward the synthesis of chitosan derivatives and their nanoparticles with enhanced antimicrobial activities. In this study, chitosan derivatives with different azides and alkyne groups were synthesized using click chemistry, and these were

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