73469

(S_P,S′_P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene

≥97%

• Synonym(s): (1R,1′R)- 1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS), Mandyphos SL-M004-1
• Empirical Formula (Hill Notation): C₆₄H₇₄FeN₂O₄P₂
• CAS Number: 494227-37-1
• Molecular Weight: 1053.08
• MDL number: MFCD04117704
• UNSPSC Code: 12352005
• PubChem Substance ID: 24886565
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: ≥97%
• form: powder
• optical purity: ee: ≥99%
• functional group: amine; phenyl; phosphine
• SMILES string: [Fe].COc1c(C)cc(cc1C)P([C]2[CH][CH][CH][C]2[C@H](N(C)C)c3ccccc3)c4cc(C)c(OC)c(C)c4.COc5c(C)cc(cc5C)P([C]6[CH][CH][CH][C]6[C@H](N(C)C)c7ccccc7)c8cc(C)c(OC)c(C)c8
• InChI: 1S/2C32H37NO2P.Fe/c2*1-21-17-26(18-22(2)31(21)34-7)36(27-19-23(3)32(35-8)24(4)20-27)29-16-12-15-28(29)30(33(5)6)25-13-10-9-11-14-25;/h2*9-20,30H,1-8H3;/t2*30-;/m11./s1
• InChI key: HEJIDMKBSDYNOY-LJXMUBMNSA-N

Description

General description

Mandyphos SL-M004-1 is a chiral ferrocenyl based diphosphine ligand belonging to the Mandyphos family.[1]

Application

It may be used as a chiral ligand in the rhodium complex-catalyzed hydrogenation reaction, a key step during the synthesis of argatroban.[2]

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

sold in collaboration with Solvias AG

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)