733210
Tetrakis(dimethylsulfoxide)dichlororuthenium(II)
96%
Synonym(s):
Dichlorotetrakis(dimethyl sulfoxide)ruthenium
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$129.00
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1 G
$129.00
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About This Item
Empirical Formula (Hill Notation):
C8H24Cl2O4RuS4
CAS Number:
Molecular Weight:
484.51
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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assay
96%
form
solid
reaction suitability
core: ruthenium
reagent type: catalyst
mp
192-198 °C
SMILES string
O=S(C)C.O=S(C)C.Cl[Ru](Cl)O=S(C)C.O=S(C)C
InChI
1S/4C2H6OS.2ClH.Ru/c4*1-4(2)3;;;/h4*1-2H3;2*1H;/q;;;;;;+2/p-2
InChI key
UMJDEUKQHKMAOI-UHFFFAOYSA-L
Related Categories
General description
Tetrakis(dimethylsulfoxide)dichlororuthenium(II), [RuCl2(dmso)4] is an organoruthenium compound. It is used as a homogeneous catalyst in organic synthesis.
Tetrakis(dimethylsulfoxide)dichlororuthenium(II) (Ru(DMSO)4Cl2) is a coordination complex generally used as a catalyst in various reactions. In addition, it is also used as a precursor in the synthesis of other ruthenium complexes. [1] [2] [3]
Tetrakis(dimethylsulfoxide)dichlororuthenium(II) (Ru(DMSO)4Cl2) is a coordination complex generally used as a catalyst in various reactions. In addition, it is also used as a precursor in the synthesis of other ruthenium complexes. [1] [2] [3]
Application
RuCl2(dmso)4 can be used as a catalyst for:
Tetrakis(dimethylsulfoxide)dichlororuthenium(II) can be used as a precursor in the synthesis of Ru(II)-MEPE (metallo-supramolecular polyelectrolytes) complex, which is used to prepare electrochromic organic-metallic hybrid polymers.[2]
- The β-alkylation of secondary alcohols via hydrogen auto-transfer process.
- The oxidation of thioethers (S) to sulfoxides by N-methylmorpholine N-oxide (NMO).
Tetrakis(dimethylsulfoxide)dichlororuthenium(II) can be used as a precursor in the synthesis of Ru(II)-MEPE (metallo-supramolecular polyelectrolytes) complex, which is used to prepare electrochromic organic-metallic hybrid polymers.[2]
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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