717657

2-Methoxy-1-naphthaleneboronic acid

• Synonym(s): (2-Methoxy-1-naphthalenyl)boronic acid, (2-Methoxy-1-naphthyl)boronic acid, 1-(2-Methoxynaphthyl)boronic acid
• Empirical Formula (Hill Notation): C₁₁H₁₁BO₃
• CAS Number: 104116-17-8
• Molecular Weight: 202.01
• MDL number: MFCD11044173
• UNSPSC Code: 12352103
• PubChem Substance ID: 329763511
• NACRES: NA.22

Properties

• form: solid
• mp: 125-130 °C
• SMILES string: COc1ccc2ccccc2c1B(O)O
• InChI: 1S/C11H11BO3/c1-15-10-7-6-8-4-2-3-5-9(8)11(10)12(13)14/h2-7,13-14H,1H3
• InChI key: NHVWTZOWDLOBBS-UHFFFAOYSA-N

Description

Application

Reactant for:

• Design of phosphorus C,P-ligands for environmentally benign cross-coupling reactions
• Sterically hindered Suzuki-Miyaura coupling
• Palladium-catalyzed cross-coupling reactions
• Deboronation homocoupling reactions
• Copper-catalyzed N-arylation of imidazoles
• Stereoselective preparation of biaryl compounds via palladium-catalyzed asymmetric Suzuki-Miyaura coupling

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable